崔鹏课题组
| 崔鹏 (Dr. Peng Cui) Email：pcui@ahnu.edu.cn Office：Liqin Building 1139 Lab：Liqin Building 1130,1131,1132 ORCID: 0000-0003-4011-4144 |
Biography
2017.7- Professor, Anhui Normal University
2015.10-2017.2 Postdoctoral Associate, University of Pennsylvania, USA（with Prof. Neil C. Tomson）
2013.10-2015.9 Postdoctoral Fellow, University of Notre Dame, USA（with Prof. Vlad M. Iluc）
2011.10-2013.9 Humboldt Postdoctoral Fellow, RWTH-Aachen University, Germany（with Prof. Jun Okuda）
2005.09-2011.1 Ph.D., Shanghai Institute of Organic Chemistry, CAS, China（with Prof. Yaofeng Chen）
2001.09-2005.8 B.S., Sichuan University, China（with Prof. Meiming Luo）
Research
General Description
杂核金属配合物对于N2, H2, O2等重要小分子的活化转化具有举足轻重的作用。生物体系中固氮酶的FeMo辅因子，光系统Ⅱ中放氧复合物的活性中心Mn4O5Ca，以及[NiFe]氢化酶，都含有两种性质不同的金属离子。在杂金属体系中，由于金属中心性质的差异，对底物进行活化时的模式和作用是不同的：1）通过金属间相互作用调控不同金属中心的电性；2）不同的金属中心对底物进行协同活化；这些传统的单金属以及同核双金属体系中是难以实现的。
和传统单金属中心的反应模式不同：1）金属-金属键中σ、π、δ键的电子具有丰富的反应性质；2）双金属的协同作用能够调节底物活化过程中的选择性和反应速率。合成表征结构新颖的含有金属-金属键的配合物，研究其与多种底物的当量或催化反应，对于揭示金属-金属键的反应性有重要的意义。
Current Interests
Heterobimetallic Rare-earth and transition metal complexes for small molecule activation & catalysis.
Metal-Metal bond chemistry involving Rare-earth metals.
Group
Current Group Members
Group Photos
Scientific Contributions
Publications at AHNU
30. "Rare-earth Metalloligand for Low Valent Cobalt Complexes: Fine Electronic Tuning via Co→RE Dative Interactions." Xiuyan He, Xiaowei Pan, Chunyan Xiong, Yun Zhang, Dongjing Hong, Huayi Fang*, Peng Cui*, Inorg. Chem., 2024, 63, 8155-8162.
29. "A scandium metalloligand supported Ni(0) complex with a heterobimetallocycle: versatile reactivity with unsaturated bonds." Lei Ma, Xiaowei Pan, Dongjing Hong, Huayi Fang*, Peng Cui*, Chem Commun., 2024, 60, 4222-4225.
28. "Tripodal tris(siloxide) ligand supported trivalent rare-earth metal complexes and redox reactivity." Hui Guo, Dongjing Hong, Peng Cui*, Dalton Trans., 2023, 52, 15672-15676
27. "Dinitrogen Complexes of Co(-I) Supported by Rare-earth Metal-Based Metalloligand." Yun Zhang, Xiaowei Pan, Min Xu, Chunyan Xiong, Dongjing Hong, Huayi Fang*, Peng Cui*, Inorg. Chem., 2023, 62, 3836-3846.
26. "Phosphinoamido Ligand Supported Heterobimetallic Rare-Earth Metal-Palladium Complexes: Versatile Structures and Redox Reactivities." Jun Du, Xiuyan He, Dongjing Hong, Shuangliu Zhou, Huayi Fang*, Peng Cui*, Dalton Trans., 2022, 51, 8777-8785.
25. "Three-Coordinate Pd(0) with Rare-earth Metalloligands: Synergetic CO Activation and Double P-C Bond Cleavage-Formation Reactions" Peng Cui*, Changjiang Wu, Jun Du, Gen Luo*, Zeming Huang, Shuangliu Zhou, Inorg. Chem., 2021, 60, 9688-9699.
24. "P-C Bond Cleavage Induced Ni(II) Complexes Bearing Rare-earth Metal-Based Metalloligand and Reactivities Toward Isonitrile, Nitrile and Epoxide" Peng Cui*, Xia Huang, Jun Du, Zeming Huang, Inorg. Chem., 2021, 60, 3249-3258.
23. "Heterobimetallic Pd(0) Complexes with Pd→Ln (Ln = Sc, Y, Yb, Lu) Dative Bonds: Rare-earth Metal Dominated Frustrated Lewis pair-like Reactivity." Jun Du, Yanan Zhang, Zeming Huang, Shuangliu Zhou*, Huayi Fang*, Peng Cui*, Dalton Trans., 2020, 49, 12311–12318.
22. "Heterobimetallic Scandium-Group 10 Metal Complexes with LM→Sc (LM = Ni, Pd, Pt) Dative Bond." Peng Cui*, Chunyan Xiong, Jun Du, Zeming Huang, Sijun Xie, Hua Wang, Shuangliu Zhou, Huayi Fang*, Shaowu Wang*, Dalton Trans., 2020, 49, 124–130.
21. "A Scandium Metalloligand Based Heterobimetallic Pd-Sc Complex: Electronic Tuning Through a Very Short Pd→Sc Dative Bond." Jun Du, Zeming Huang, Yanan Zhang, Shaowu Wang, Shuangliu Zhou*, Huayi Fang*, Peng Cui*, Chem. Eur. J. 2019, 25, 10149–10155.
Publications Before AHNU
20. "Oxidation Reactions of a Nucleophilic Palladium Carbene: Mono and Bi-radical Carbenes." Peng Cui, Melissa R. Hoffbauer, Mariya Vyushkova, Vlad M. Iluc*, Dalton Trans., 2019, 48, 9663-9668.
19. “Ring Size Modulated Reactivity of Putative Dicobalt Bridging Nitrides: C–H Activation vs. Phosphinimide Formation.” Peng Cui, Qiuran Wang, Sam P. McCollom, Brian C. Manor, Patrick J. Carrol, Neil C. Tomson*, Angew. Chem. Int. Ed. 2017, 56, 15979–15983.
18. “Molecular Magnesium Hydrides Supported by an Anionic Triazacyclononane-Type Ligand.” S. Schnitzler, P. Cui, T. P. Spaniol and J. Okuda*, Dalton Trans., 2017, 46, 1761-1765.
17. “Boratabenzene Rare-earth Metal Complexes.” Peng Cui, Yaofeng Chen*, Coord. Chem. Rev. 2016, 314, 2-13.
16. “C-H Activation of Ethers by Pyridine Tethered PCsp3P-type Iridium Complexes” Peng Cui, Dominic C. Babbini, Vlad M. Iluc*, Dalton Trans., 2016, 45, 10007-10016.
15. “Heterobimetallic Pd-K Carbene Complexes via One-Electron Reductions of Palladium Radical Carbenes.” Peng Cui, Melissa R. Hoffbauer, Mariya Vyushkova, Vlad M. Iluc*, Chem. Sci., 2016, 4444-4452.
14. “Redox-Induced Umpolung of Transition Metal Carbenes.” Peng Cui, Vlad M. Iluc*, Chem. Sci., 2015, 6, 7343-7354.
13. “Frustrated Lewis Pair-Like Reactions of Nucleophilic Palladium Carbenes with B(C6F5)3.”Peng Cui, Cezar C. Comanescu, Vlad M. Iluc*, Chem. Commun., 2015, 51. 6206-6209.
12. “An Ion Pair Scandium Hydride Supported by a Dianionic (NNNN)-Type Macrocycle Ligand.”Peng Cui, Thomas P. Spaniol, Laurent Maron*, Jun Okuda*, Chem. Commun., 2014, 50, 424-426.
11. “Dehydrogenation of Amine–Borane Me2NH·BH3 Catalyzed by A Lanthanum Hydride Complex.” Peng Cui, Thomas P. Spaniol, Laurent Maron*, Jun Okuda*, Chem. Eur. J. 2013, 19, 13437-13444.
10. “Heterometallic Potassium Rare–Earth Metal Allyl and Hydrido Complexes Stabilized by A Dianionic (NNNN) Macrocyclic Ancillary Ligand.” Peng Cui, Thomas P. Spaniol, Jun Okuda*, Organometallics,2013, 32, 1176-1182.
9. “Synthesis and Catalytic Activity of Amido-Boratabenzene Complexes of Rare-Earth Metals and Zirconium and Chromium.” Xiufang Wang, Weijie Peng, Peng Cui, Xuebing Leng, Wei Xia, Yaofeng Chen*, Organometallics, 2013, 32, 6166-6169.
8. “Boratatrozircenes: cycloheptatrienyl zirconium boratabenzene sandwich complexes–evaluation of potential η6–η5 hapticity interconversions.” Andreas Gl?ckner, Peng Cui, Yaofeng Chen, Constantin G. Daniliuc, Peter G. Jones and Matthias Tamm*, New. J. Chem. 2012, 36, 1392-1398.
7. “Versatile Reactivities of ansa-Heteroborabenzene Divalent Ytterbium Amide toward Alkali–Metal Salts and the Generation of Heterometallic Ytterbium–Alkali–Metal Boratabenzene Complexes.”Peng Cui, Yaofeng Chen*, Guangyu Li and Wei Xia, Organometallics, 2011, 30, 2012-2017.
6. “Synthesis, and Structure Characterization of Solvent-free Divalent Ytterbium Bis(boratabenzene) and (Cyclopentadienyl)(Boratabenzene) Complexes.” Peng Cui, Yaofeng Chen*, Qiang Zhang, Guangyu Li, Wei Xia, J. Organomet. Chem., 2010, 695, 2713-2719.
5. “Neodymium(ш) phosphinidene complexes supported by pentamethylcyclopentadienyl and hydrotris(pyrazolyl)borate ligands. Peng Cui, Yaofeng Chen*, Maxim V. Borzov, Dalton Trans., 2010, 39, 6886-6890.
4. “An unprecedented lanthanide phosphinidene halide: synthesis, structure and reactivity.” Peng Cui, Yaofeng Chen*, Xin Xu and Jie Sun, Chem. Commun., 2008, 5547-5549.
3. “An ansa-Heteroborabenzene Divalent Lanthanide Amide Through C-H Bond Cleavage.” Peng Cui, Yaofeng Chen*, Guangyu Li and Wei Xia, Angew. Chem. Int. Ed. 2008, 47, 9944-9947.
2. “Divalent Ytterbium Boratabenzene Complex (C5H5BNPh2)2Yb(THF)2: Synthesis, Structure, and Solvent-Mediated Redox Transformation.” Peng Cui, Yaofeng Chen*, Guoping Wang, Guangyu Li and Wei Xia, Organometallics, 2008, 27, 4013-4016.
1. “Boratabenzene Derivatives of Divalent Samarium: Synthesis, Structures and Catalytic Reactivities of (C5H5BXPh2)2Sm(THF)2 (X = N, P).” Peng Cui, Yaofeng Chen*, Xiaohua Zeng, Jie Sun, Guangyu Li and Wei Xia, Orgnometallics, 2007, 26, 6519-6521.
Publications in Books
2. “Scandium Complexes” Peng Cui, Vol. 4, Chapter 2 in “Comprehensive Coordiantion Chemistry III”, Elsevier, 2022.
1. “Pincer-Carbenoid Complexes with Late-transition Metals: Synthesis, Electronic Structure and Reactivity.” Peng Cui, Vlad M. Iluc, Chapter 17 in “Pincer Compounds---Chemistry and Applications”, Elsevier, 2018.
Invites Talks & Lectures
1. “基于电子可调控的大环配体双铁、双钴氮化物化学”，口头报告，第16届江淮有机化学论坛，苏州大学，2018年10月
2. “基于LM-Ln配键的稀土-后过渡金属杂核配合物”，邀请报告，第10届全国无机化学学术会议，山东大学，2019年8月
3. “基于LM-Ln配键的稀土-后过渡金属杂核配合物”，邀请报告，第6届全国稀土金属有机化学讨论会，苏州大学，2019年10月
4.“Exploring the Chemistry of Heterobimetallic Rare-earth/Late-Transition Metal Complexes”，invited talk in "angular momentum" symposia sponsored by Robinson group at Brown University，2022年3月29日
5. “Syntheses and Reactivity of Heterobimetallic Rare-earth/Late-transition Metal Complexes with LM-Ln Dative Bond”，邀请报告，第8届亚洲配位化学会议，台北，2022年8月
6. “稀土-后过渡金属键配合物的合成及反应性研究”，口头报告，第21届全国金属有机化学学术讨论会，安徽工程大学/必赢线路检测3003，2022年8月
7. “稀土-后过渡金属键配合物的合成及反应性”，口头报告，中国化学会第33届学术年会，青岛，2023年6月
8. “稀土-后过渡金属键配合物的合成与反应性探索”，邀请报告，第七届全国稀土金属有机化学学术会议，上海，2023年10月