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商永嘉


http://210.45.192.123:8080/_vsl/32F1E42D07A1F1E828DA4A0936301411/C72B1453/2491D?e=.jpg

商永嘉 教授 博士 博士生导师

邮 箱：shyj@ahnu.edu.cn

实验室：花津校区理科大楼1133-1134

办公室：花津校区理科大楼1136

ORCID：https://orcid.org/0000-0001-9873-9150
 

所受教育

  1. 2000 年 9 月 - 2003 年 3 月 浙江大学化学系博士研究生，获理学博士学位

  2. 1994 年 9 月 - 1997 年 7 月 南京大学化学化工学院硕士研究生，获理学硕士学位

  3. 1988 年 9 月 - 1992 年 7 月 阜阳师范大学化学系学习，获学士学位

   

职称职位

  1.1997年7月至今 必赢线路检测3003助教，讲师，教授（2004年）

  2. 2006年2月--2006年8月，香港大学化学系博士后研究员

  3. 2010年4月，博士生导师

  4. 2009年2月--2012年2月，必赢线路检测3003副院长

  5. 2012年2月-2018年8月，研究生院副院长

  6. 2018年8月-至今，功能分子固体教育部重点实验室主任

   

主持项目

  1. 多反应中心卡宾中间体参与的环状化合物的高效合成反应研究，国家自然科学基金面上项目(21772001)，64万，2018-2021，主持。

  2. 基于环状重氮-1,3-二酮的过渡金属催化的有机反应及其在复杂化合物合成中的应用，国家自然科学基金面上项目(21372008)，80万，2014-2017，主持。

  3. 有机催化的串联反应及其在复杂化合物分子合成中的应用，国家自然科学基金面上项目(21172001)，60万，2012-2015，主持。

  4. 教育部“新世纪优秀人才支持计划”(NCET-10-0004)，50万，2011-2014，主持。

  5. 基于烯酮亚胺的多组分反应合成一些环状化合物的方法学研究，国家自然科学基金面上项目(20872001)，35万，2009-2011，主持。

  6. 清洁化生产电子级异氰脲酸三缩水甘油酯(TGIC)及其副产物的开发研究，安徽省教育厅产学研重点项目(KJ2010A137)，5万，2010-2012，主持。

   

主持教学项目

  1. 主持安徽省省级精品课程《有机化学》

 

研究领域

  1. 有机合成与药物合成

  2. 金属参与的有机合成反应

  3. 应用有机化学

 

讲授课程

  1. 有机化学

  2. 有机合成

  3. 综合化学实验

  4. 诺贝尔奖与科学精神

 

获奖与人才情况

  1. 2020年获必赢线路检测3003教学名师

  2. 2019年安徽省学术和技术带头人

  3. 2019年安徽省科学技术进步奖三等奖(第二完成人)

  4. 2017年安徽省科学技术奖三等奖(第一完成人)

  5. 2010年安徽优秀青年科技创新奖

  6. 2010年获安徽省高等学校省级教学成果二等奖（排名第一）

  7. 2009年安徽省学术和技术带头人后备人选

  8. 2005年获安徽省高校中青年学科带头人培养对象

  9. 2004年获必赢线路检测3003优秀教学二等奖

  10. 2003年获安徽省高校中青年优秀骨干教师

 

组内新闻

  1. 2020/12/18 祝贺课题组胡汪成同学的文章被Org. Biomol. & Chem.杂志接受，论文题目为"Construction of isoxazolone-fused phenanthridines via Rh-catalyzed cascade C-H activation/cyclization of 3-arylisoxazolones with cyclic 2-diazo-1,3-diketones".

  2. 2020/12/14 祝贺课题组左有鹏同学的文章被Adv. Synth. & Catal. 杂志接受，论文题目为""Palladium-Catalyzed 5-exo-dig Cyclization Cascade, Sequential Amination/Etherification for Stereoselective Construction of 3-Methyleneindolinones". The manuscript has been selected as a VIP.

  3. 2020/10/28 祝贺课题组洪浩然同学的文章被Adv. Synth. & Catal. 杂志接受，论文题目为"Enantioselective Michael Addition Reactions to Construct CF3S-containing Stereocenter Catalyzed by Chiral Quaternary Phosphonium Salts".

  4. 2020/10/19祝贺课题组周彤彤同学的文章“Rh-catalyzed formal [3+2] cyclization for synthesis of 5-aryl-2-(quinolin-2-yl)oxazoles and its applications in metal ions probes”被Chin. J. Chem. 杂志接受。

  5. 2020/8/28 祝贺课题组洪浩然同学的文章被Chin. Chem. L. 杂志接受，论文题目为"Organophosphine bearing multiple hydrogen-bond donors for asymmetric Michael addition reaction of 1-oxoindane-2-carboxylic acid ester via dual-reagent catalysis".

  6. 2020/04/25祝贺课题组左有鹏同学的文章“Palladium-catalyzed Cascade Decarboxylative Amination/6-endo-dig Benzannulation of o-Alkynylarylketones with N-Hydroxyamides to Access Diverse 1-Naphthylamine Derivatives ”被Org. Lett. 杂志接受。

  7. 2020/02/25祝贺课题组刘源同学的文章“Palladium-catalysed dearomative aryl/cycloimidoylation of indoles. ”被Chem. Commun. 杂志接受，并邀请作为做封面文章。

  8. 2020/02/23 祝贺课题组杨晨同学的文章“Rh(III)-Catalyzed Relay Double Carbenoid Insertion and Diannulation of Sulfoximine Benzamides with α‑Diazo Carbonyl Compounds: Access to Furo[2,3‑c]isochromenes. ”被Org. Lett. 杂志接受，并邀请作为做封面文章。

  9. 2019/03/20 祝贺课题组蔡晓婷同学的文章被Org. Biomol. & Chem.杂志接受，论文题目为"Synthesis of 4-styrylcoumarins via FeCl3-promoted cascade reactions of propargylamines with β-keto esters"。

  10. 2019/08/20 祝贺课题组刘艳飞同学的文章被Org. Biomol. & Chem.杂志接受，论文题目为"Controllable construction of isoquinolinedione and isocoumarin scaffolds via RhIII-catalyzed C–H annulation of N-tosylbenzamides with diazo compounds"。

  11. 2019/08/20 祝贺课题组左有鹏同学的文章被Org. Biomol. & Chem.杂志接受，论文题目为"Substituent-Oriented C–N Bond Formation via N–H Insertion or Wolff Rearrangement of 5-Aryl-1H-pyrazoles and Diazo Compounds"。

  12. 2019/05/21 祝贺课题组蔡盼圆同学的文章被Org. Chem. Front. 杂志接受，论文题目为"Tuneable Access to Isoquinolines via a Transition-Metal-Free C(sp3)-C(sp3) Bond Cleavage Rearrangement Reaction"。

  13. 2019/04/29 祝贺课题组宁翊同学的文章被Adv. Synth. & Catal.杂志接受，论文题目为"Rh2(OAc)4-Catalyzed Cyclization of Pyrazol-5-amines and 1,3-Diketone-2-Diazos using DMF as CH Sources: Access to Pyrazolo[3,4-b]pyridines"。

  14. 2019/02/14 祝贺课题组李欠欠同学的文章被Adv. Synth. & Catal. 杂志接受，论文题目为"Base-mediated 1,4-Conjugate Addition/Intramolecular 5-exo-digAnnulation of Propargylamines with Benzoylacetonitriles andβ-Keto Esters for Polysubstituted Furans and Furo[3,4-c]coumarins Formation"。

  15. 2018/10/21 祝贺课题组韩光同学的文章被Tetrahedron杂志接受，论文题目为"Rh(III)-catalyzed C-H activation of primary benzamides and tandem cyclization with cyclic 2-diazo-1,3-diketones for the synthesis of isocoumarins"。

  16. 2018/10/09 祝贺课题组左有鹏同学的文章被J. Org. Chem.杂志接受，论文题目为"Selective Synthesis ofAminoisoquinolinesviaRh(III)-catalyzed C-H/N-H Bond Functionalization ofN-Aryl Amidines with Cyclic 2-Diazo-1,3-diketones"。

  17. 2018/09/08 祝贺课题组王慧同学的文章被Org. Biomol. & Chem.杂志接受，论文题目为"FeCl3-promoted Tandem 1,4-Conjugate Addition/6-endo-digCyclyzation/Oxidation of Propargylamines and Benzoylacetonitriles/Malononitrile: Direct Access to Functionalized 2-Aryl-4H-chromenes"。

  18. ◎2018/07/01 祝贺2015级王慧、张兰兰两位同学通过硕士论文答辩并获得硕士学位，感谢他们为课题组所做出的贡献！祝他们前程似锦！

  19. 2017/12/11 祝贺课题组陶佳佳同学的文章被Tetrahedron杂志接受，论文题目为"Synthesis of Polysubstituted Phenyl AcetatesviaFeCl3-mediated Domino Reaction of 2-(Aryl(piperidin-1-yl)methyl)phenols and 1,3-Diketones"。

  20. 2017/11/17 祝贺课题组左有鹏同学的文章被ACS Omega杂志接受，论文题目为"Rh(III)-Catalyzed C-H Activation/Intramolecular Cyclization: Access toN-Acyl-2,3-dihydro-1H-carbazol-4(9H)-ones from Cyclic 2-Diazo-1,3-diketones andN-Arylamides"。

  21. 2017/08/14 祝贺课题组于智宇同学的文章被Org. Biomol. & Chem.杂志接受，论文题目为"Direct Carboxamidation of Cyclic 2-Diazo-1,3-diketones by Rh2(OAc)4-catalyzedIsocyanide Insertion-Hydrolysis"。

  22. 2017/07/01 祝贺2014级张家星同学通过博士论文答辩并获得博士学位，2014级杨成、陶佳佳、蔡晓婷、项立伟四位同学通过硕士论文答辩并获得硕士学位，感谢他们为课题组所做出的贡献！祝他们前程似锦！

  23. 2017/06/19 祝贺课题组时光好同学的文章被Chin. J. Chem.杂志接受，并被选为杂志封面，论文题目为"Oxidative Rearrangement of Isatins with ArylaminesUsing H2O2as Oxidant: A Facile Synthesis of Quinazoline-2,4-diones and Evaluation of Their Antibacterial Activity"。

  24. 2017/01/20 祝贺课题组杨成同学的文章被J. Org. Chem.杂志接受，论文题目为"Synthesis of Isocoumarins from Cyclic 2-Diazo-1,3-diketones and Benzoic AcidsviaRh(III)-catalyzed C?H Activation and Esterification"。

  25. 2016/12/07 祝贺课题组周尧同学的文章被ACS Omega杂志接受，论文题目为"Synthesis of 2-Arylimino-6,7-dihydrobenzo[d][1,3]oxathiol-4(5H)-onesviaRh2(OAc)4-catalyzed [3+2] Cycloaddition Reactions of Cyclic 2-Diazo-1,3-diketones with Aryl Isothiocyanates"。

  26. 2016/10/31 祝贺课题组张志琴同学的文章被Chem. Res. Chin. Univ.杂志接受，论文题目为"Ferrocenyl-isoxazole Derivative: A NovelElectrochemical, Colorimetric, and Fluorescent Multiple Signal Probe for Highly Selective Recognition ofCu2+Ions"。

  27. 2016/10/25 祝贺课题组张家星、陶佳佳两位同学获得国家奖学金！

  28. 2016/09/14 祝贺课题组张家星同学的文章被Org. Lett.杂志接受，论文题目为"Thiourea?Quaternary Ammonium Salt Catalyzed Asymmetric 1,3?Dipolar Cycloaddition of Imino Esters To Construct Spiro[pyrrolidin-3,3′-oxindoles]"。

  29. 2016/08/26 祝贺课题组张家星同学的文章被J. Org. Chem.杂志接受，论文题目为"Enantioselective Construction of Spirocyclic OxindolesviaTandem Michael/Michael Reactions Catalyzed by Multifunctional Quaternary Phosphonium Salt"。

  30. 2016/08/03 祝贺课题组时光好同学的文章被Chin. J. Chem.杂志接受，论文题目为"Synthesis of 3',4'-Diaryl-4'H-spiro[indoline-3,5'-[1',2',4']oxadiazol]-2-onesviaDMAP-catalyzed Domino Reactions and Their Antibacterial Activity"。

  31. 2016/07/01 祝贺2013级韩光、王婕、吴福丽三位同学通过硕士论文答辩并获得硕士学位，感谢他们为课题组所做出的贡献！祝他们前程似锦！

  32. 2016/02/15 祝贺课题组陶佳佳同学的文章被J. Org. Chem.杂志接受，论文题目为"FeCl3-mediated One-pot Domino Reactions for the Synthesis of 9-Aryl/9-Arylethynyl-2,3,4,9-tetrahydro-1H-xanthen-1-ones from Propargylic amines/Diaryl Amines and1,3-Cyclohexanediones"。

  33. 2016/01/19 祝贺课题组时光好同学的文章被RSCAdv.杂志接受，论文题目为"Combinatorial Synthesis of Spiro[indoline-3,2'-pyrrole] Derivativesviaa Three-component Reaction under Catalyst-free Conditions

 

代表性论文


  1. Enantioselective Construction of 1H-Isoindoles Containing Tri- and Difluoromethylated Quaternary Stereogenic Centers via Palladium-Catalyzed C−H Bond Imidoylation. Jian Wang,* Lianjie Li, Minxue Chai, Shumin Ding, Jing Li, Yongjia Shang,* Haixia Zhao, Dan Li, and Qiang Zhu.* ACS Catal. 2021, 11, 12367–12374.

  2. Jiaping Wu*, Baiyang Qian, Lili Lu, Haitao Yang, Yongjia Shang* and Jitan Zhang. Access to the C2 C–H olefination, alkylation and deuteration of indoles by rhodium(iii) catalysis: an opportunity for diverse syntheses. Org. Chem. Front. 2021,8, 3032-3040.

  3. Yinsong Wu, Xinwei He*, Mengqing Xie, Ruxue Li, Yi Ning, Jiahui Duan, Enshen Zhang, and Yongjia Shang.* Rh(III)-Catalyzed Cascade Nucleophilic Addition/Annulation of 2-Diazo-1,3-diketones with 1,3-Dicarbonyl Compounds To Access 6,7-Dihydrobenzofuran-4(5H)-ones. J. Org. Chem. 2021, 86,7370–7380.

  4. Li-Qin Yan, Zhenzhen Yin, Xinwei He,* Qianqian Li, Ruxue Li, Jiahui Duan, Keke Xu, Qiang Tang, and Yongjia Shang.* Copper-Catalyzed Cascade 1,4-Addition/Annulation/Hydrolysis of Propargylamines with 2 Hydroxynaphthalene-1,4-diones: Direct Formation of 12-Phenacyl-11H benzo[b]xanthenes. J. Org. Chem. 2021, 86, 4182−4192.

  5. Tongtong Zhou, Xinwei He,* Youpeng Zuo, Yuhao Wu, Wangcheng Hu, Shiwen Zhang, Jiahui Duan, and Yongjia Shang.* Rh-Catalyzed Formal [3+2] Cyclization for the Synthesis of 5-Aryl-2-(quinolin-2-yl)oxazoles and Its Applications in Metal Ions Probes. Chin. J. Chem. 2021, 39, 621-626.

  6. Youpeng Zuo, Xinwei He, Qiang Tang, Wangcheng Hu, Tongtong Zhou, Wenbo Hu, Yongjia Shang.* Palladium-Catalyzed 5-exo-dig Cyclization Cascade, Sequential Amination/Etherification for Stereoselective Construction of 3-Methyleneindolinones. Adv. Synth. Catal.2021, 363, 2117-2123.

  7. Wangcheng Hu, Xinwei He, * Tongtong Zhou, Youpeng Zuo, Shiwen Zhang, Tingting Yang and Yongjia Shang.* Construction of isoxazolone-fused phenanthridines via Rh-catalyzed cascade C–H activation/cyclization of 3-arylisoxazolones with cyclic 2-diazo-1,3-diketones.Org. Biomol. Chem., 2021, 19, 552.

  8. Xinwei He,* Ruxue Li, Pui Ying Choy, Mengqing Xie, Jiahui Duan, Qiang Tang, Yongjia Shang,* Fuk Yee, Kwong.* A Cascade Double 1,4-Addition/Intramolecular Annulation Strategy for Expditious Assembly of Unsymmetrical Dibenzofurans. Commun. Chem., 2021, 4, 42.

  9. HaoranHong, HongyuWang, ChangwuZheng, GangZhao*, YongjiaShang*.Organophosphine bearing multiple hydrogen-bond donors for asymmetric Michael addition reaction of 1-oxoindane-2-carboxylic acid ester via dual-reagent catalysis. Chinese Chemical Letters.2021,32, 708-712.

  10. Zuo, Youpeng; He, Xinwei*; Tang, Qiang; Hu, Wangcheng; Zhou, Tongtong; Yongjia Shang *. Palladium-Catalyzed Cascade Decarboxylative Amination/6-endo-dig Benzannulation of o-Alkynylarylketones with N-Hydroxyamides to Access Diverse 1-Naphthylamine Derivatives.Org. Lett., 2020, 22,10, 3890-3894.


  11. Jian Wang, * Yuan Liu, Zhuang Xiong, Ling Zhong, Shumin Ding, Lianjie Li, Haixia Zhao, Chen Chen and Yongjia Shang *. Palladium-catalysed dearomative aryl/cycloimidoylation of indoles. Chem. Commun., 2020, 56, 3249-3252.  （封面文章）

    http://210.45.192.123:8080/_vsl/65B64E77A1B62BFC48188914F6032D52/687F411B/1A131

  12. Chen Yang, Chen Chen, Shunfan Li, Xinwei He, Youpeng Zuo, Wangcheng Hu, Tongtong Zhou, Jian Wang,* and Yongjia Shang*, Rh(III)-Catalyzed Relay Double Carbenoid Insertion and Diannulation of Sulfoximine Benzamides with α Diazo Carbonyl Compounds: Access to Furo[2,3 c]isochromenes. Org. Lett., 2020, 22,7, 2506-2511.（封面文章）

    http://210.45.192.123:8080/_vsl/7A6F202B713592380CA00E8911689C50/3A8BA9CE/123D3

  13. Jian Wang,* Panyuan Cai, Yimiao He, Yuan Liu, Ling Zhong, Shumin Ding, and Yongjia Shang*, “Tuneable Access to Isoquinolines via a Transition-Metal-Free C(sp3)-C(sp3) Bond Cleavage Rearrangement Reaction”. Org. Chem. Front., 2019, 6, 2430–2434.

    http://210.45.192.123:8080/_vsl/0DC99062B862418030AFAA2F2ECDE77D/9926E2EC/838A

  14.  Yi Ning, Xinwei He, Youpeng Zuo, Panyuan Cai, Mengqing Xie, Jian Wang,* and Yongjia Shang*, Rhodium (II) Acetate-Catalysed Cyclization of Pyrazol-5-amine and 1,3-Diketone-2-diazo Compounds using N,N-Dimethylformamide as a Carbon-Hydrogen Source: Access to Pyrazolo[3,4-b]pyridines. Adv. Synth. & Catal.,2019, 361, 3518-3524.

    http://210.45.192.123:8080/_vsl/75920EBD8FBC985EEB91062B06C7D28B/52719C99/60DA

  15.  Li-Qin Yan, Xiaoting Cai, Xinwei He,* Hui Wang, Mengqing Xie, Youpeng Zuo, Yongjia Shang*, Synthesis of 4-styrylcoumarins via FeCl3-promoted cascade reactions of propargylamines with β-keto esters. Org. Biomol. & Chem., 2019, 17,4005-4013.

  16.  Qianqian Li, Xinwei He,* Jiajia Tao, Mengqing Xie, Hui Wang, Ruxue Li, and Yongjia Shang *, Base-mediated 1,4-Conjugate Addition/Intramolecular 5-exo-dig Annulation of Propargylamines with Benzoylacetonitriles and β-Keto Esters for Polysubstituted Furans and Furo[3,4-c]coumarins Formation. Adv. Synth. & Catal.,2019,361,1874-1886.

    http://210.45.192.123:8080/_vsl/39DBD8A1EF9D66A6CFCF633C9298807E/C85F30A0/517C

  17. Xinwei He,* Guang Han, Youpeng Zuo, Yongjia Shang*, Rh(III)-catalyzed C-H Activation of Primary Benzamides and Tandem Cyclization with Cyclic 2-Diazo-1,3-diketones for the Synthesis of Isocoumarins. Tetrahedron, 2018, 74 , 7082-7088.

    http://210.45.192.123:8080/_vsl/4B7C732D87F5EA978D499EE4BE95DE2D/4F1ED1A7/7E17

  18.  Youpeng Zuo, Xinwei He, Yi Ning, Yuhao Wu, and Yongjia Shang*,Selective Synthesis of Aminoisoquinolines via Rh(III)-catalyzed C-H/N-H Bond Functionalization of N-Aryl Amidines with Cyclic 2-Diazo-1,3-diketones. J. Org. Chem. 2018, 83, 13463−13472.

    http://210.45.192.123:8080/_vsl/8E1A5D179718A7DD12EEFB1D813C621A/0A421F87/7350

  19. Xinwei He,* Hui Wang, Xiaoting Cai, Qianqian Li, Jiajia Tao, andYongjia Shang.* FeCl3-promoted Tandem 1,4-Conjugate Addition/6-endo-digCyclyzation/Oxidation of Propargylamines and Benzoylacetonitriles/Malononitrile: Direct Access to Functionalized 2-Aryl-4H-chromenes.Org. Biomol. Chem.,2018,16, 7191-7202.

    http://210.45.192.123:8080/_vsl/B641F575155F3EB8E434D5D83B19F72C/58D3A54C/A968?e=.jpg

  20.  Youpeng Zuo, Xinwei He, Yi Ning, Lanlan Zhang, Yuhao Wu,Yongjia Shang.* Divergent Synthesis of 3,4-Dihydrodibenzo[b,d]furan-1(2H)-ones and IsocoumarinsviaAdditive-controlled Chemoselective C-C or C-N Bond Cleavage.New J. Chem.,2018,42, 1673-1681.

    http://210.45.192.123:8080/_vsl/BFDB0EE33CD54501A6D33523E2DBADE2/01F45BED/9FE0?e=.jpg

  21. Youpeng Zuo, Xinwei He, Yi Ning, Yuhao Wu,Yongjia Shang.* Rh(III)-Catalyzed C-H Activation/Intramolecular Cyclization: Access toN-Acyl-2,3-dihydro-1H-carbazol-4(9H)-ones from Cyclic 2-Diazo-1,3-diketones andN-Arylamides.ACS Omega,2017,2, 8507-8516.

    http://210.45.192.123:8080/_vsl/61912B9B567C8475A1F44F4A5B0335B7/0B664345/66D1?e=.jpg

  22. Guanghao Shi, Xinwei He,Yongjia Shang,* Cheng Yang, Liwei Xiang. Oxidative Rearrangement of Isatins with Arylamines Using H2O2as Oxidant: A Facile Synthesis of Quinazoline-2,4-diones and Evaluation of Their Antibacterial Activity.Chin. J. Chem.,2017,35, 1835-1843. (Front Cover)

    http://210.45.192.123:8080/_vsl/11DDCD07C93C4CEA55989FD0867F9FD1/56B17BD6/19D5B?e=.png

  23.  Xinwei He,* Jiajia Tao, Hui Wang, Xiaoting Cai, Qianqian Li,Yongjia Shang.* Synthesis of polysubstituted phenyl acetatesviaFeCl3-mediated domino reaction of 2-(aryl(piperidin-1-yl)methyl) phenols and 1,3-diketones.Tetrahedron,2017,73, 7017-7023.

    http://210.45.192.123:8080/_vsl/BAA08F0B0341FFD97718CC8662D1452E/103661B4/6F97?e=.jpg

  24.  Xinwei He,* Zhiyu Yu, Youpeng Zuo, Cheng Yang,Yongjia Shang.* Direct Carboxamidation of Cyclic 2-Diazo-1,3-diketones by Rh2(OAc)4-catalyzed Isocyanide Insertion-Hydrolysis.Org. & Biomol. Chem.,2017,15, 7127-7130.

    http://210.45.192.123:8080/_vsl/D844F806376226A8C6CFBFB9DBB774BE/14714E8F/8603?e=.jpg

  25. Cheng Yang, Xinwei He, Lanlan Zhang, Guang Han, Youpeng Zuo,Yongjia Shang.* Synthesis of Isocoumarins from Cyclic 2-Diazo-1,3-diketones and Benzoic AcidsviaRh(III)-catalyzed C-H Activation and Esterification.J. Org. Chem.,2017,82, 2081-2088.

    http://210.45.192.123:8080/_vsl/78805CB3BCCB2ED6B69A61F2701B1C04/87047C97/916F?e=.jpg

  26. Jia-Xing Zhang, Hong-Yu Wang, Qiao-Wen Jin, Chang-Wu Zheng, Gang Zhao,*Yong-Jia Shang.* Thiourea-Quaternary Ammonium Salt Catalyzed Asymmetric 1,3-Dipolar Cycloaddition of Imino Esters To Construct Spiro[pyrrolidin-3,3′-oxindoles].Org. Lett.,2016,18, 4774-4777.

    http://210.45.192.123:8080/_vsl/66F1C47C48B934AF3B27DDA46420B91F/72FAF2B6/490D?e=.jpg

  27. Jiaxing Zhang, Dongdong Cao, Hongyu Wang, Changwu Zheng, Gang Zhao,*Yongjia Shang.* Enantioselective Construction of Spirocyclic Oxindoles via Tandem Michael/Michael Reactions Catalyzed by Multifunctional Quaternary Phosphonium Salt.J. Org. Chem.,2016,81, 10558-10568.

    http://210.45.192.123:8080/_vsl/1E7D48316705B6E9C0554561E4BED98D/9FA0386D/740F?e=.jpg

  28. Zhiqin Zhang, Xinwei He,Yongjia Shang,* Zhiyu Yu, Sufan Wang, Fuli Wu. Ferrocenyl-isoxazole Derivative: A Novel Electrochemical, Colorimetric, and Fluorescent Multiple Signal Probe for Highly Selective Recognition of Cu2+Ions.Chem. Res. Chin. Univ.,2017,33, 31-35.

    http://210.45.192.123:8080/_vsl/727A846D072D2495E65F27104338D4D7/AB2DF864/61D1?e=.jpg

  29. Guanghao Shi, Xinwei He,Yongjia Shang,* Liwei Xiang, Cheng Yang, Guang Han, Bing Du.* Synthesisof 3',4'-Diaryl-4'H-spiro[indoline-3,5'-[1',2',4']oxadiazol]-2-onesviaDMAP-catalyzed Domino Reactions and Their Antibacterial Activity.Chin. J. Chem.,2016,34, 901-909.

    http://210.45.192.123:8080/_vsl/C027EA8125C4499F7DDB4C796C500E44/CBE85825/8AC5?e=.jpg

  30. Xinwei He, Yao Zhou,Yongjia Shang,* Cheng Yang, Youpeng Zuo. Synthesis of 2-Arylimino-6,7-dihydrobenzo[d][1,3]oxathiol-4(5H)-onesviaRh2(OAc)4-catalyzed Reactions of Cyclic 2-Diazo-1,3-diketones with Aryl Isothiocyanates.ACS Omega,2016,1, 1277-1283.

    http://210.45.192.123:8080/_vsl/714F94068E178845E58938ABCFCA9877/BA1C62A5/6915?e=.jpg

  31.  Xinwei He, Jiajia Tao, Xiaoqian Hu, Hui Wang,Yongjia Shang.* FeCl3-mediated One-pot Domino Reactions for the Synthesis of 9-Aryl/9-Arylethynyl-2,3,4,9-tetrahydro-1H-xanthen-1-ones from Propargylic amines/Diaryl Amines and 1,3-Cyclohexanediones.J. Org. Chem.,2016,81, 2062-2069.

    http://210.45.192.123:8080/_vsl/22706256DF50A232E4B1B17D347BCC33/87071943/4E44?e=.jpg

  32.  Guanghao Shi, Xinwei He,Yongjia Shang,* Meihua Xie.* Combinatorial Synthesis of Spiro[indoline-3,2'-pyrrole] Derivativesviaa Three-component Reaction under Catalyst-free Conditions.RSC Adv.,2016,6, 10412-10418.

    http://210.45.192.123:8080/_vsl/AAD15BBD9C9EE6452B4532187B48EF1B/A450F13D/82AE?e=.jpg

  33. Yongjia Shang,* Xiaoqian Hu, Xinwei He, Jiajia Tao, Guang Han, Fuli Wu, and Jie Wang. FeCl3-Mediated Synthesis of β-Alkynyl Ketones via Domino Nucleophilic-Substitution/Intramolecular-Cyclization/Reverse Claisen Condensation ofN-Cyclohexyl Propargylamines and 1,3-Diketones.J. Org. Chem.,2015,80, 4760-4765.

    http://210.45.192.123:8080/_vsl/E996E621E72826F7DD1A2FCCAF560642/7139A089/5662?e=.jpg

  34.  Xinwei He,Yongjia Shang,* Zhiyu Yu, Mei Fang, Yao Zhou, Guang Han, Fuli Wu. FeCl3-Catalyzed Four-component Nucleophilic Addition/Intermolecular Cyclization Yielding Polysubstituted Pyridine Derivatives.J. Org. Chem.,2014,79, 8882-8888.

    http://210.45.192.123:8080/_vsl/FC9D4D8EE6E0B573EAC170A5511ED493/6A59E868/53AA?e=.jpg

  35.  Xinwei He,Yongjia Shang,* Yao Zhou, Zhiyu Yu, Guang Han, Wenjing Jin, Jiaojiao Chen. Synthesis of Coumarin-3-carboxylic EstersviaFeCl3-Catalyzed Multicomponent Reaction of Salicylaldehydes, Meldrum’s Acid and Alcohols.Tetrahedron,2015,71, 863-868.

    http://210.45.192.123:8080/_vsl/7DEC27999B5F3B04B0F034282B6B3317/BBD48DEA/6883?e=.jpg

  36.  Jiaxing Zhang, Dongdong Cao, Hongyu Wang, Gang Zhao,* and Yongjia Shang.* Enantioselective Desymmetrization of meso-Aziridines with Aaromatic Thiols Catalyzed by Chiral Bifunctional Quaternary Phosphonium Salts Derived froma-Amino Acids.Tetrahedron,2015,71, 1785-1791.

    http://210.45.192.123:8080/_vsl/7671C4ACF05C30353157A5F99812898F/CF9C9F62/474A?e=.jpg

  37.  Zhiqiang Niu, Xinwei He, Yongjia Shang.* Efficient Enantioselective Synthesis of Dihydropyrans via Organocatalytic Michael Addition Reaction.Tetrahedron: Asymmetry,2014,25, 796-801.

    http://210.45.192.123:8080/_vsl/F3A0C54DABF48D33482CF4DEF590D2EF/76B8D3D8/71EE?e=.jpg

  38.  Manman Hu, Xinwei He, Zhiqiang Niu, Zhenglei Yan, Fuyin Zhou,Yongjia Shang.* Synthesis of 3,4,5-Trisubstituted Isoxazoles by 1,3-Dipolar Cycloaddition Reaction fromα-Azidoacrylates and Aromatic Oxime.Synthesis,2014,46, 510-514.

    http://210.45.192.123:8080/_vsl/F768A1DD38D1E24ABB7B61430C28AAFE/C5E052A1/35B6?e=.jpg

  39. Jianglai Cheng, Yong Wang, Chao Teng,Yongjia Shang,* Lianbing Ren, Biwang Jiang.* Preparation and Characterization of Monodisperse, Micrometer-sized, Hierarchically Porous Carbon Spheres as Catalyst Support.Chem. Eng. J.,2014,242, 285–293.

    http://210.45.192.123:8080/_vsl/725B12A3638DEF6EEEFA8585FBFEE2BE/E9B1A828/BBD7?e=.png

  40. Shuyan Yu, Zhiqin Zhang, Zhiyu Yu,Yongjia Shang.* Novel Isoxazoline Ligand with Ferrocene Backbone: Preparation and Application in Heck Reaction with Water as Solvent.Appl. Organometal. Chem.,2014,28, 657–660.

    http://210.45.192.123:8080/_vsl/7E85ABF17846AF6300292197810751C2/66489D7C/8722?e=.jpg

  41.  Yongjia Shang,* Kaisheng Liao, Xinwei He, Jinsong Hu. One-Pot Synthesis of Disulfide-linkedN-Sulfonylazetidin-2-iminesvia a Copper-catalyzed Multicomponent Cascade Reaction.Tetrahedron,2013,69, 10134–10138.

    http://210.45.192.123:8080/_vsl/E79F538238349199ADB3155EA357A95E/A9C70CA9/3E7A?e=.jpg

  42.  Jiaping Wu,Yongjia Shang,* Cuie Wang, Xinwei He, Zhenglei Yan, Manman Hu, Fuyin Zhou. Synthesis of 3,4-Dihydro-2H-1,4-Benzo[b]thiazine DerivativesviaDABCO-Catalyzed One-Pot Three-Component Condensation Reactions.RSC Adv.,2013,3, 4643–4651.

    http://210.45.192.123:8080/_vsl/5B5A69F094A3059B10A964E8DA15C438/BEA2080A/3976?e=.jpg

  43. Yongjia Shang,* Lifen Wang, Xinwei He, Min Zhang. Novel Syntheses of Pyrrolo[2,1-a]isoquinolines via 1,3-Dipolar Cycloaddition between N-Ylides and Alkynes.RSC Adv.,2012,2, 7681–76881.

    http://210.45.192.123:8080/_vsl/13FDC7FB9F9CF291BF26302B33BA4EA7/EF0B3278/31EA?e=.jpg

  44. Yongjia Shang,* Kai Ju, Xinwei He, Jinsong Hu, Shuyan Yu, Min Zhang, Kaisheng Liao, Lifen Wang, and Ping Zhang. Copper-Catalyzed Multicomponent Reaction: Synthesis of 4-Arylsulfonylimino-4, 5-dihydrofuran Derivatives.J. Org. Chem.,2010,75, 5743–5745.

    http://210.45.192.123:8080/_vsl/11858AF5689E2BF17E4D783B8186BD49/FEE9C801/48D7?e=.jpg

  45.  Yongjia Shang,* Cuie Wang, Xinwei He, Kai Ju, Min Zhang, Shuyan Yu, Jiaping Wu. DMAP-catalyzed Cascade Reaction: One-pot Synthesis of Benzofurans in Water.Tetrahedron,2010,66, 9629–9633.

    http://210.45.192.123:8080/_vsl/3755E95B4D90C2EB50474D0C54C91EBF/30466A5D/3337?e=.jpg

  46. Yongjia Shang,* Xinwei He, Jinsong Hu, JianweiWu, Min Zhang, Shuyan Yu, and Qianqian Zhang. Copper-Catalyzed Efficient Multicomponent Reaction: Synthesis of Benzoxazoline-Amidine Derivatives.Adv. Synth. Catal.,2009,351, 2709–2713.

    http://210.45.192.123:8080/_vsl/ADB9424DB5C2977AB93E92D81E7EC941/BA808CA6/3743?e=.jpg

  47. Jie Wang, Shu-Guang Chen, Bing-Feng Sun*, Guo-Qiang Lin,* and Yongjia Shang. Collective Total Synthesis of Englerin A and B, Orientalol E and F, and Oxyphyllol: Application of the Organocatalytic [4+3] Cycloaddition Reaction.Chem. Eur. J.,2013,19, 2539–2547.

  48. Jinsong Hu,Yongjia Shang, Xiaoqiang Yao, Ling Qin, Yizhi Li, Zijian Guo, Hegen Zheng,* and Ziling Xue. Syntheses, Structures, and Photoluminescence of Five New Metal-Organic Frameworks Based on Flexible Tetrapyridines and Aromatic Polycarboxylate Acids.Cryst. Growth. Des.,2010,10, 2676–2684.

  49. Yongjia Shang,* Min Zhang, Shuyan Yu, Kai Ju, Cuie Wang, Xinwei He. New Route Synthesis of Indolizines via 1,3-Dipolar Cycloaddition of Pyridiniums and Alkynes.Tetrahedron Lett.,2009,50, 6981–6984.

  50. Yongjia Shang,* Zhijun Feng, Lili Yuan, Shaowu Wang. Diastereoselective Cycloadditions of a Soluble Polymer-supported Substituted Allyl Alcohol Derived from Baylis–Hillman Reaction with Nitrile Oxides.Tetrahedron,2008,64, 5779–5783.

 

研究成果

  1. 商永嘉，顾家山，等. 氯乙酰氯的合成和研究，2000年8月通过安徽省教育厅鉴定。

 

会议论文

  1. Xinwei He,* Jiajia Tao, Hui Wang,Yongjia Shang.* Synthesis of Polysubstituted Phenyl Acetates via FeCl3-mediated Domino Reaction of 2-(Aryl(piperidin-1-yl)methyl)phenols and 1,3-Diketones. 第十届全国有机化学学术会议, 中国, 深圳, 2017年12月19-21日.

  2. Youpeng Zuo, Xinwei He,Yongjia Shang.* Divergent Synthesis of 3,4-Dihydrodibenzo[b,d]furan-1(2H)-ones and Isocoumarinsvia Additive-controlled Chemoselective C-C or C-N Bond Cleavage. 第十届全国有机化学学术会议, 中国, 深圳, 2017年12月19-21日.

  3. Xinwei He, Yao Zhou,Yongjia Shang.* Synthesis of 2-Iimino-[1,3]oxathioles via Rh2(OAc)4-catalyzed [3+2] Cycloaddition Reactions of Cyclic 2-Diazo-1,3-diketones with Aryl Isothiocyanates. 第十九届全国金属有机化学学术讨论会, 中国, 杭州, 2016年10月28-31日.

  4. Xinwei He, XiaoqianHu, Jiajia Tao, Hui Wang, Xiaoting Cai,Yongjia Shang.* FeCl3-catalyzed Domino Reactions of Propargylic Amines and Activated Methylene Compounds. 第十三届全国有机合成化学学术研讨会, P29, 中国, 扬州, 2016年10月13-16日.

  5. Xiaoqian Hu, Xinwei He, Jiajia Tao,Yongjia Shang.* FeCl3-catalyzed One-pot Tandem Reactions of N-cyclohexyl Propargylamines and 1,3-Diketones. 第九届全国有机化学学术会议, P360, 中国, 长春, 2015年7月28-31日.

  6. 何心伟，商永嘉.* FeCl3催化的基于芳醛、活泼亚甲基化合物的“一锅”串联反应/多组分反应合成香豆素/吡啶衍生物的研究. 第十二届江淮有机化学论坛, 中国， 芜湖， 2014年10月31日-11月2日.

  7. 何心伟， 朱东盛， 蒋畅，商永嘉.* 室温无溶剂无催化剂下的Knoevenagel缩合反应研究. 第八届有机化学学术会议暨首届重庆有机化学国际研讨会， P794， 中国， 重庆， 2013年10月17-20日.

  8. Xinwei He, Kaisheng Liao, Zhenglei Yan, Fuyin Zhou, Manman Hu, Yongjia Shang.* One-step Synthesis of Polysubstituted N-Sulfonylazetidin-2-imines viaCopper-catalyzed Sequential Multicomponent/S-S Coupling Reaction. 第十七届全国金属有机化学学术讨论会, P209,中国, 北京, 2012年10月19-22日.

  9. Min Zhang, Shuyan Yu, Yongjia Shang.* General and direct synthesis of indolozines via 1,3-dipolar cycloaddition of pyridiniums and alkynes. 第六届全国有机化学会议, P340, 中国, 西安, 2009年8月17-20日.

  10. Shuyan Yu, Min Zhang, Yongjia Shang.* Synthesis of Two Novel bisoxazoline ligands and Application to Palladium-catalyzed Heck-Sonogashira Coupling Reaction. 第六届全国有机化学会议, P153, 中国, 西安, 2009年8月17-20日.

 

专利

  1. 叶青青，左有鹏，何心伟，商永嘉. 1,2,3-三取代中氮茚衍生物及其制备方法.中国发明专利，专利号:201810293794.3，公开日: 2018.09.14.

  2. 李欠欠，何心伟，陶佳佳，商永嘉. 多取代呋喃衍生物及其制备方法. 中国发明专利，专利号:201810227907.X，公开日: 2018.08.24.

  3. 武玉豪，何心伟，左有鹏，商永嘉. 香豆素-4-磺酸酯衍生物及其制备方法. 中国发明专利，专利号:201810034868.1，公开日: 2018.07.20.

  4. 左有鹏，何心伟，商永嘉. 异香豆素衍生物的制备方法. 中国发明专利，专利号:201710416486.0，公开日: 2017.09.01.

  5. 何心伟，商永嘉，琚凯. 3,4,5-三取代噁唑烷酮类化合物及其制备方法. 中国发明专利，专利号: 201410557565.X，公开日: 2015.02.04.

  6. 何心伟，靳文静，陈娇娇，商永嘉. 一种香豆素-3-羧酸酯衍生物的制备方法. 中国发明专利，专利号:201310642930.2，公开日: 2014.03.12.

  7. 商永嘉，赵敏，何心伟，孙宇. 絮凝剂组合物，中国发明专利. 专利号: ZL 201110222749.7.

  8. 商永嘉，琚凯，程杰，王桂蕾. 一种阿德福韦的制备工艺. 中国发明专利，专利号: ZL 20071001914.7.


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